Thanks mate.
An individual weighing 200 lbs. who just sat (MET's value = 1) for 30 minutes would burn approximately 48 calories. Although this would be a catabolic effect, it would not have an overall negative effect on your system. You have to remember that the body is always in a catabolic state to some degree. It only becomes a concern when you are engaged in physical activity and you don't replenish nutrient and energy reserves/requirements. The real concern would be if you suffered from cachexia which is far more serious.
It is important to eat on a regular basis and to try to keep something inside you at all times to keep nitrogen and GH levels high. It is not, however, required that you eat immediately upon waking up. If you were in a cutting cycle, I would be advising you to perform 30-60 minutes of cardio as soon as you wake up, followed by a healthy breakfast.
If you are going to use any type of supplement then the supplement should adapt to your schedule and not the other way around. If you are finding that you are just too hungry to have to wait then the best advice is not to use the supplement. The supplement you have mentioned is not necessary in obtaining a good physique.
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KP -- Fitness Basics