5x5 gets the weight up at expense of speed and volume. The rep range may be adequate for the chosen compound, although it won't work for everyone (in terms of your goal).
Isolations vary in effectiveness... many rely on improved leverages; the body responds with extreme tension, and you won't get that from quarter squats and pulley systems. Leg extensions take out the hams, which are important for tension in the quads and keep the knee healthy.
lateral raises are good.. the body don't do much of that in everyday life, so you can get some pretty unusual muscle shape from those.
Some things to consider:
Correct tensions -which means attention to form particularly with difficult compounds- appropriate stresses, which can be gauged by feel.
Attention to volume and speed- Too fast and the weight maybe too low... too much workload equals poor fatigue management, extra calories and subsequently poorer performance.
Individual recovery and bodytype- This means you should tailor your sets, workload, exercise frequency and exercise selection according to these two factors. This is something only you can answer.
Don't prioritize with 50% isolations.