Yes, take 1 LipoStim in the morning and start with 1 LipoFlame (since you are taking them together) pre workout. Once your body gets used to that, or if you don't feel anything, take 1 LipoStim in the morning and 2 Lipoflames. You can continue this process to get the desired effect. Do not take anymore than 4 LipoFlame's at a time.
You won't need to take anything mid day. The LipoStim3 is a once a day fat burner so it is not needed anymore than that. The LipoFlame just intensifies your workout and your body doesn't need that rush any other time.